Valencia travel to the Estadio municipal de Santo Domingo on Sunday to face Alcorcon in the Copa del Rey round of 32.Having dispatched the lowly Terrassa and Yeclano with a combined score of 8-3 in the previous rounds, the Bats are in good form in the competition.That's in stark contrast to their run in La Liga, which has yielded only four wins from 18 games, as Javi Garcia's side languish 14th in the standings.However, they will be glad to know that Alcorcon are currently mired in troubles of their own.The Potters are currently 20th in the Segunda Division and facing a long relegation scramble ahead of them.In the cup so far, they narrowly beat Lealtad and Real Zaragoza in the previous rounds, winning 2-1 on both occasions.They have caused quite a few surprises in the competition in the past and are now looking to reach the last-16 for the first time since the 2016-17 season.Alcorcon vs Valencia Head-To-HeadThis will be the first official meeting between the sides.🎦 @rubensobrino1: "I think that we have to pay just as much attention to the Copa del Rey as LaLiga"#AMUNTValencia 🦇— Valencia CF 🦇🍊🌊 (@valenciacf_en) January 14, 2021Alcorcon Form Guide (all competitions): D-W-W-L-WValencia Form Guide (all competitions): L-L-D-W-WAlcorcon vs Valencia Team NewsAlcorconThe home side have all of their players available as there are no injury concerns going into the match and no suspensions to deal with either.Injured: NoneSuspended: NoneUnavailable: NoneNuevo entrenamiento completado 💛🙌 para seguir preparando el partido de #CopaDelRey https://t.co/LhEErf6W4A pic.twitter.com/A8a2wiVpoU— A.D. Alcorcón (@AD_Alcorcon) January 14, 2021ValenciaThe 2019 winners won't have goalkeeper Jasper Cillessen and striker Kevin Gamiero available for selection due to injuries. However, centre-back Guillem Molina, who was sent off in the first round, is available again after serving his one-game ban.Injured: Jasper Cillessen and Kevin GamieroSuspended: NoneUnavailable: NoneAlcorcon vs Valencia Predicted XIAlcorcon (4-1-4-1): Samuel Casado; Javi Castro, Fidel Escobar, Jose Leon, Carlos Bellvis; Juanma Bravo; Ernesto Gomez, Reko, Hugo Fraile, Alvaro Juan; Marc Gual.Valencia (4-4-2): Juame Domenech; Thierry Correira, Mouctar Diakhaby, Hugo Guillamon, Jose Gaya; Daniel Wass, Carlos Soler, Uros Racic, Denis Cheryshev; Lee Kang-in, Maxi Gomez.Alcorcon vs Valencia PredictionAlcorcon are going to make it difficult for Valencia at home, but the visitors have a much stronger squad. The visitors can count on the talent of Carlos Soler, who is having the best season of his career. It should be another high-scoring victory for the La Liga outfit.Prediction: Alcorcon 1-4 Valencia